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    • 专利摘要:
    16 ABSTRACT An in-line production method for providing a liquid flow of at least oneadditive in the short circulation and into the liquid flow of a paper makingstock of a fiber web machine by feeding, the liquid flow of the at least oneadditive to the liquid flow of the short circulation, wherein a suitable amount ofa microfibrillated cellulose or nanofibrillated polysaccharide is providedsubstantially simultaneously with the feeding of liquid flow of the at least oneadditive. Elected for publication: Fig. 2
    公开号:SE1251278A1
    申请号:SE1251278
    申请日:2012-11-09
    公开日:2014-05-10
    发明作者:Olavi Imppola；Jouni Matula；Jussi Matula；Karri Tahkola；Isto Heiskanen；Matti Väkeväinen；Jari Räsänen
    申请人:
    IPC主号:
    专利说明:

    Technical Documents The present documents relate to an in-line production method for a papermaking and board production process, and for the simultaneous introduction of at least one additive and microfibrillated cellulose into the short circulation of a papermaking process. More specifically, the present document relates to the crystallization and precipitation of calcium carbonate in an in-production process.
    Background To level the surface of a paper, a filler has been added that fills the gaps that do not consist of paper fiber. This leads, for example, to improved printability, size resistance, shape and gloss. In addition to this, the optical properties of the paper, such as opacity, light scattering and brightness, are usually also improved, since the scattering coefficient and the brightness are often higher for the filler than for the pulp.
    Since fillers are cheap in relation to trafiber, they are used in papermaking to reduce the cost of raw materials. In addition, drying paper towels containing fillers requires less energy. Despite the low price of fillers and positive effects on paper properties, they also have negative features. They affect the bonds between the fibers by adsorption or formation on the fiber surfaces. Due to the part, the tensile strength and tensile stiffness of the paper are reduced and when printing, lint can arise. Use of paper machines can also occur due to fillers. The adhering shape of the fillers is also quite substandard which can lead to the versatility of the paper.
    When it comes to packaging cardboard, fillers are used in very small amounts compared to other types of paper. The fact that the fillers increase the weight of the cardboard without giving strengthening properties, and that they reduce the caliber at the same basis weight, are typical reasons why they are not used. When it comes to bending stiffness, the caliber of the paper is the most important parameter. Fillers also reduce the modulus of elasticity, which is an important parameter for flexural stiffness.
    Formatted 2 Bleached pulp is often used in the top layer of the paper. The aim of this is to obtain higher brightness, and an overall improved appearance has the cardboard. Even in these cases, small amounts of fillers are used and usually quite expensive ones such as TiO 2, calcined kaolin and so on are used to optimize the modulus of elasticity of the top layer and maximize the flexural stiffness of the cardboard. In many cases, the basis weight of the top layer is optimized for whiteness and lightness, and the visual appearance is instead optimized with respect to maximum flexural stiffness.
    Thus, there is a need to be able to improve the whiteness and opacity of the topsheet of the paper while maintaining the rigidity while using inexpensive fillers.
    A common filler in papermaking is precipitated calcium carbonate (FCC). Usually, the FCC has been produced separately from the papermaking process itself. The FCC is normally manufactured at a dedicated plant near the paper mill.
    WO 2011110744 A1 describes a method and a reactor for inline production of calcium carbonate (FCC, precipitated calcium carbonate) in connection with the production process for a fibrous web. It refers to inline production of FCC in a suspension in the production of fibrous webs, preferably it is preferred that the production take place directly in the flow of the fibrous mass in one of the sub-rivers, or a filtered river, present in the fibrous mass production. This method has several advantages such as reduced investment costs, as there is no need for a separate plant for the production of FCC. Furthermore, the need for chemicals for adhesion is reduced as the FCC at least partially precipitates directly on the fibers.
    EP 2287398 A1 describes a method for obtaining calcium carbonate, in which fiber and fiber fibril containing a composition are likely to be obtained, in which the calcium carbonate particles are if necessary connected with fibrils and fibers, which are characterized by good dewatering ability and for papermaking with a high amount of filler, with high filler. and star specific volume. This invention is achieved by a combination of four methods: by using special calcium carbonate particles, which are (d 50) and have a diverse morphology and have an average particle diameter of between 2.5-4 μm, by setting a weight ratio of fibril to calcium carbonate particles. in the composition before the coincidence to between 0.2: 1 and 4: 1, by using fiber fibril and by setting a weight ratio of calcium carbonate ions against the fibrill before the coincidence to between 0.02: 1 3 and 0.2: 1. However, this method describes a traditional stand-alone process for precipitated calcium carbonate using carbon dioxide and calcium hydroxide with fiber.
    There is thus a need for a new process for manufacturing a cardboard layer with a uniform visual appearance, but also with an optimized modulus of elasticity.
    Summary It is an object of the contents of the present application to provide an improved method of feeding additives into the short circulation having a fiber forming machine. Said web may also be part of a layer in a multilayer paper or board structure. The feed additives can also be considered as a separate layer forming a multilayer paper structure as described, for example, in US 2005034827.
    A specific object of the contents of the present application is to provide an improved method of in-line precipitation of calcium carbonate into the short circulation.
    The purpose is achieved in whole or in part by a method according to the appended independent requirement. Embodiments are described in the appended dependent claims and in the following description and drawings.
    According to a first aspect, an in-line reduction method is provided for supplying a liquid stream of at least one tsatsine portion to the short circulation and into the liquid stream of papermaking machine of a fibrous web mask. , in which case there are two or more additives, the method comprises more difficult to allow (Jesse to react with each other; wherein the method comprises crystallization of a filler and wherein said additive Or carbon dioxide and calcium hydroxide (lime milk), there is called carbon dioxide. Calcium hydroxide is introduced into the short circulation, whereby an amplicl of microlibrillated cellulose or nanofibrillated ore saccharide is provided essentially at a certain time in the intake of the liquid stream of the two titrates, so that the additional or refractory cell is formed or the cells are formed. The cellulose and then form compounds form the i-microfibrillated cellulose.
    By "additive" is meant a reactive additive which reacts pre-pressing the web or in the short circulation, which means that the additive in the presently invented method may be a filler material or a fiber composite filler material.
    By the said in-line production method a method is obtained for feeding additives, such as calcium hydroxide (lime milk) and carbon dioxide to the short circulation, which can be mixed with microfibrillated cellulose (MFC) so that the advantageous properties of this mixture are thereby obtained. Said additives may, for example, affect or initiate nucleation on the cellulosic surface or precipitate on the surface of microfibrillated cellulose and thereby form compositions with the MFC which have improved or altered properties compared to the additives which are fed into the short circulation without the addition of MFC or additives that react before the MFC Or present.
    It may therefore be possible, for example, to "glue together" MFC fiber with the help of different types of additives which fall out in the straightforward part of the papermaking process, such as dissolved cellulose.
    According to an uldringeferrn how the forgta agpskten can the method, when it media-dray 0 By said method an "in-line production" of unlit calcium carbonate (PCC, Precipitated Calcium Carbonate) is provided which is thus produced directly into the short circulation has the paper machine. Such methods are described in, for example, US 2011000633 and WO 2011/110744.
    The use of MFC or so-called nanocellulose in papermaking has been studied to a fairly large extent. It has been found that Oven am MFC improves the strength properties (including the modulus of elasticity which is important for the topsheet of the paper) so the porosity and shrinkage are reduced at the same time as a result of drying Okar. This has negative effects on, for example, cardboard production and cardboard properties in such a way that the porosity is reduced as a result of the MFC, which leads to risks such as decanting. The drying of a layer of low porosity gives rise to the inside of the paperboard which cannot be released fast enough and the paperboard is delaminated.
    In addition, the MFC increases the shrinkage during drying and small-scale drying will increase the surface roughness of the cardboard and lead to poor print quality. Furthermore, it is unlikely that an in-line FCC process will provide a clean paper machine system as the need for adhering chemicals is much less (or significantly reduced).
    By combining an in-line FCC process with the supply or dosing of microfibrillated cellulose (MFC), a number of improvements have been observed, for example in top layer application. The whiteness and evenness of the paper Okar and the turbidity of white surfaces decreases.
    The modulus of elasticity increases for the same porosity and the whiteness is improved.
    By using in-line FCC, the costs of process chemicals are reduced and there is an increase in the purity of the cardboard machine process, which is shown by fewer hub breaks, fewer impurities and the lack of accumulations in pipelines.
    It has surprisingly been discovered that the precipitation of PCC particles rather takes place on the surface of small particles that exist in the process waters, which is also linked to the solid surface area, high surface energy and pH properties of these small particles.
    An "appropriate amount" of MFC refers to an amount that is sufficient to interact with the calcium hydroxide and further provide an effective amount of FCC on or in the MFC. The amount may vary depending on the final product of the papermaking mold, but as an example the dosage of MFC may be between 5-50 kg / ton for a paperboard topsheet and FCC between 1-20% (10-200 kg / ton) of the topsheet origin and the desired properties of the top layer.
    By adding microfibrillated cellulose or "nanocellulose" (MFC) substantially simultaneously with the calcium hydroxide in the in-line reactor for further reaction with carbon dioxide, which corresponds to the described method for producing MFC-PCC material and thus the amount of salt span needed to obtain a satisfactory whiteness and visual appearance, while still having the ability to control shrinkage due to drying and maintain the improvement of modulus of elasticity, can be easily controlled as most of the calcium carbonate precipitates on the MFC particles or in the MFC solution.
    Thus, by adding or dosing MFC in an in-line FCC process, a method is obtained to control the amount of uncorinated material, as the surface pH and chemistry of the MFC can be adjusted, which means that the particle size and dimensions have the FCC added to the short circulation or the fiber milling flow can be controlled. Furthermore, by the PCC particles being on the MFC surface, the porosity of the paperboard can be controlled, shrinkage due to drying can be controlled and the improved modulus of elasticity obtained as a result of MFC can be maintained. By having PCC particles on the top layer of the cardboard, the whiteness and printability of the cardboard can be improved without reducing the bending stiffness.
    Since in-line PCC is a relatively inexpensive filler, the cost of paperboard can be reduced, in relation to the use of more expensive fillers to obtain the optical properties.
    There is also an improvement in bile purity for the cardboard manufacturing machine.
    According to one embodiment, the feed into the short circulation can take place by injecting at least one additive and / or microfibrillated cellulose into the liquid stream of papermaking mill. The feed to the short circulation can be effected by injecting at least either carbon dioxide, calcium hydroxide and / or microfibrillated cellulose into the paper mill of the paper mill.
    According to an alternative embodiment, the carbon dioxide, calcium hydroxide and / or the microfibrillated cellulose can be fed in separately by injection.
    By "MFC is supplied substantially simultaneously" is meant that carbon dioxide, calcium hydroxide and MFC are fed into the liquid stream at the same time and in close proximity to each other.
    According to an alternative embodiment, the microfibrillated cellulose can be provided in the liquid stream of papermaking mill and the calcium hydroxide and carbon dioxide can be fed in separately or simultaneously by injection.
    By "provided substantially simultaneously" in this case is meant that MFC is present in the liquid stream and that the calcium hydroxide and the carbon dioxide are released simultaneously or separately (and in close proximity to each other).
    According to a further alternative embodiment, the calcium hydroxide and the microfibrillated cellulose can be mixed together for injection into the liquid stream of papermaking mill and the carbon dioxide can be fed in separately from the mixture of calcium hydroxide and microfibrillated cellulose.
    By "provided substantially simultaneously" is meant in some cases that the calcium hydroxide and the MFC are mixed before they are fed into the liquid stream of papermaking mill and that the carbon dioxide is fed in separately but in the vicinity of the mixture. According to a further alternative embodiment, the microfibrillated cellulose can be mixed with other optional additives and the mixture can be fed in separately from the feed of calcium hydroxide and carbon dioxide.
    The injection into the liquid stream of papermaking mold can be performed from one or more nozzles in a direction substantially transverse to the direction of the liquid stream, and at a flow rate higher than that of the liquid stream.
    This rapid precipitation reaction, or rapid addition and subsequent reaction of calcium hydroxide and carbon dioxide in the ground stream, provides an easy way to precipitate PCC as crystals, i.e. the precipitation of calcium carbonate on MFC is formed very quickly. This can promote the formation of new types of filler-fiber compositions in which the PCC forms new types of crystals on the surface of the MFC.
    The liquefaction of papermaking mold may contain atm instone one of the following components: kidney pulp, long fiber pulp, short pulp, mechanical pulp, chemomechanical pulp, chemical pulp, microfiber pulp, nanofiber pulp), recycled pulp suspension, pulp fiber, pulp fiber, , regenerated cellulose fibers, solution mass, state suspension and filtrates containing solid parts.
    According to an alternative embodiment, the fibrous web can also be formed into foam, that is to say a substance which is produced by the formation of gas pockets in a liquid or solid form, and not only in liquid or aqueous form.
    Description of drawings Embodiments of the present solution will now all be described by way of example, with reference to the accompanying schematic drawings in which: Fig. 1 schematically shows a short circulation arrangement according to prior art.
    Fig. 2 schematically shows a short circulation arrangement according to an embodiment of the invention.
    Figs. 3a-b schematically show a short circulation arrangement according to an alternative embodiment of the invention. Fig. 4 schematically shows a short circulation arrangement according to a further alternative embodiment of the invention.
    Fig. 5 schematically shows a short circulation arrangement according to a further alternative embodiment of the invention.
    Description of embodiments Definition of nanofibrillated polysaccharide This definition includes bacterial cellulosic or nanocellulosic either with traditional weaving techniques or with 0 electrostatic weaving. The fibers can also be formed in other ways, for example by ionic water shoes or membrane technology (precipitation or coagulation of dissolved cellulose), and thus either a form of regenerated cellulose or liberated fibril is obtained by selective dissolving water shoes. In these cases, the material is preferably a polysaccharide but not limited to a single polysaccharide.
    Microcrystalline cellulose, so-called whiskers and nanocellulose crystals are also included in this definition. Said component may also be a mixture of the materials presented or a combination of organic and synthetic nanofibers. 0 Definition of microfibrillated cellulose The microfibrillated cellulose (MFC) is also called nanocellulose. It is a material that is usually made of tracellulose fiber, both from hard and soft trafiber. It can also form Iran microbial calluses, agricultural fibers such as wheat bran, bannbu or other non-trafi fiber calluses. In microfibrillated cellulose, the individual microfibrils or base fibrils have been partially or completely separated from each other. A microfibrillated cellulose fibril is normally very thin (-20 nm) and the length is often between 100 nm to 10 μm. However, the microfibrils can also be longer, for example between 10-200 microns, and lengths of 2000 microns may be due to large length distribution. Fibers that have become fibrillated and that have microfibrils on the surface, as well as microfibrils that are separated and in the aqueous phase for sludge are included in the definition for MFC. In addition, whiskers are also included in the definition of MFC.
    MFC, nanocellulose or nanocrystalline cellulose can be manufactured in different ways such as mechanical, chemical, enzymatic, by using bacteria 9 or by combining, for example, chemical and mechanical treatment steps.
    Different types of spinning and precipitation processes can also be used.
    In this case, the starting material for making nanofiber or MFC may be a polysaccharide.
    Although microfibrillated cellulose (MFC) is close to the modulus of elasticity of paper, it is not good for the topsheet of paper due to reduced porosity (poor porosity / modulus of elasticity ratio) and increased shrinkage on drying.
    However, there is a need to increase the whiteness for different types of cardboard, but it has not been possible before with fillers in an efficient manner due to reduction of the modulus of elasticity. For duplex type cardboard (3-layer cardboard with a brown middle layer) Do this by increasing the top layer basis weight (and 3 `) / 0 fillers).
    Definition of precipitated calcium carbonate (PCC) Nastan alit PCC Ors by direct carbonation of aqueous lime, the so-called calcium hydroxide process. Calcium oxide (CaO) is mixed with water to form slaked lime, lime milk or calcium hydroxide.
    Calcium hydroxide, also called lime milk in this application, and carbon dioxide are mixed and allowed to react to form an unlined calcium carbonate (PCC). PCC can then be used as a filler in paper, cardboard, special paper such as cigarette paper, laminating paper, etc. PCC can also be used for surface gluing of paper or cardboard, or as a pigment in coating minerals or in chevron layers. The said PCC can also be used as a filler in plastic. The definition of unlit calcium carbonate also includes the possibility to include other metal (11) oxides which are mixed with water such as Mg (OH) 2.
    Definition of the in-line process for precipitated calcium carbonate By "in-line production" is meant that the precipitated calcium carbonate (PCC) is formed directly inside the river by papermaking mill, ie. the trapped carbon dioxide is combined with weak calcium hydroxide in the inline production, instead of that production taking place separately in the Iran papermaking process. Separate production of PCC also requires the use of holding materials to make the PCC adhere to the fibers. An in-line PCC process can generally be described as a cleaner paper machine system, and there is a reduced need for adhering chemicals. An in-line FCC process is described, for example, in WO 2011/110744.
    Figure 1 shows a prior art method for in-line production of precipitated calcium carbonate, as described in US 2011/0000633 and a schematic process arrangement for a papermaking machine 2. The backwater F is transported, for example, to a mixing tank or filtration tank 4, to which various fiber components are added for preparation of papermaking mold. Based on tests, at least one of 0 new pulp suspensions (long fiber pulp, short fiber pulp, mechanical pulp, chemomechanical pulp, chemical pulp, microfiber pulp, nanofiber pulp), recycled pulp suspension (recycled pulp, recycled pulp, fiber fractions from fibrous pulp, parts to the mixing tank, and is transported therefrom by a mixing pump 14 to a vortex cleaner 16, where heavier particles are separated. The remainder of the vortex cleaning proceeds to a gas separation tank 18, where air and / or other gases are removed from the papermaking mold. The papermaking mold is then transported to a feed pump 20 in the inlet tray, which pumps the papermaking mold to a so-called inlet tray screen, where large particles are separated from the papermaking mold. The acceptance part is transported to the papermaking machine 2 through its inlet tray. However, the short circulation of fiber weaving machines that create less demanding end products may not include a vortex cleaner, gas separation plant and / or inlet barn.
    In previous known processes, PCC production is carried out in the short circulation with the papermaking machine, before the vortex cleaning plant 16. The carbon dioxide (CO2) is supplied on the pressure side of the vortex cleaner and the calcium hydroxide (MoL) is added a few meters after the carbon dioxide has dissolved in the same tube. However, it is conceivable that this PCC production can take place closer to the inlet, or that the distance between the injectors is very small, so that carbon dioxide and calcium hydroxide are in fact injected in the same place in the short circulation. This depends on the requirements of the final product and the design of the papermaking machine.
    According to the invention, an in-line production method is provided in which additives such as carbon dioxide, calcium hydroxide etc. are fed into the short circulation of a papermaking machine, i.e. into the fibrous web or papermaking mold, and where an appropriate amount of a microfibrillated cellulose, MFC, is substantially provided while these additives are fed into the short circulation.
    What is meant by "substantially simultaneously" may vary as described below, however, it should be understood in this context that MFC is provided as the additive, such as e.g. The FCC can be formed, which can be crystallized on or in the MFC.
    When two or more additives are fed into the short circulation, they are preferably allowed to react with each other, which means that they are fed into the short circulation in such a way that the additives are allowed to react, in the case of calcium hydroxide and carbon dioxide so that calcium carbonate precipitates. formed on or in the MFC.
    According to an embodiment of the present invention, an in-line FCC process is combined with the dosing of MFC into the in-line PCC process. This entails a completely new way of providing the FCC with, for example, a fiber web in a papermaking process.
    In one embodiment of the present invention, as shown in Figure 2, calcium hydroxide, carbon dioxide and MFC are injected separately into the short circulation and fibrous web of the papermaking machine. In an alternative embodiment, shown in Figures 3a and 3b, MFC is provided e.g. during the preparation of the papermaking mold, and thus it is included in the papermaking mold, and the carbon dioxide and the calcium hydroxide are injected separately (Figure 3a) or simultaneously (Figure 3b) into the short circulation.
    In a further alternative embodiment, as shown in Figure 4, the calcium hydroxide and MFC are mixed before being injected into the short circulation and the carbon dioxide is injected separately from this mixture. In a further alternative embodiment, shown in Figure 5, MFC is mixed with other additives and this mixture is injected separately from the calcium hydroxide and the carbon dioxide.
    In all the embodiments described above, it should be understood that the order of injection of additives, i.e. Calcium hydroxide, carbon dioxide, MFC and other possible additives may occur in a different order or at a different stage in the short circulation. It is conceivable that the injection takes place very close to the inlet, or that the MFC is dosed before the addition of carbon dioxide or that the distance between the "injection points" Or shorter or longer On 12 described above. Thus, MFC, calcium hydroxide and carbon dioxide can be injected into the short circulation at essentially the same injection point.
    The point or points where injection takes place form a "PCCreaction zone".
    According to one embodiment, the MFC provides an increased fiber surface area on which the FCC can precipitate or to which calcium hydroxide can react, resulting in a more efficient precipitation of calcium carbonate.
    By modifying and adjusting surface energy, surface pH and surface chemistry for the MFC, a completely new salt is provided to control how the PCC crystals are formed on the MFC surface. The crystals formed on the surface of the MFC particle can have different shapes and configurations.
    By combining the in-line PCC process with a dosage or an addition of MFC, a new way is obtained to control the papermaking process without, for example, modifying the entire backwater circulation.
    Furthermore, when using the fibrous web to form a top layer, a number of improvements have been observed, such as increased whiteness of the cardboard and also reduced turbidity of white surfaces and an increase in surface roughness. There is also an increase in the modulus of elasticity for the same porosity as well as an improved 0 whiteness.
    By using PCC, the costs of process chemicals are reduced and there is an increase in the purity of the cardboard machine process through fewer hub breaks, fewer impurities and the lack of accumulations in pipelines.
    EP 1219344 B1 truly describes an apparatus which is particularly breathable bile homogeneously adding a liquid chemical into a liquid stream. In this method, a mixing nozzle is used and the liquid chemical is fed into the mixing nozzle, a second liquid is introduced into the same mixing nozzle in such a way that the chemical and the second liquid are brought into contact with each other substantially while the chemical is released at high speed together with the second liquid from the mixing nozzle into the process liquid transversely to the process liquid flowing in the river channel. The chemical and the other liquid can be relaxed directly into the fiber suspension that flows towards the paper machine's inlet tray. The second liquid may be a circulating liquid from the paper process such as backwater, or it may be fresh water depending on the requirements of the liquid core ikal ien to be added to the fiber stream. The flow rate from the mixing nozzle can be about four times as high as the flow rate of the fiber suspension in which the kernel and the second liquid are released.
    By using this type of rapid mixing of calcium hydroxide and MFC, a method of forming PCC crystals on MFC is obtained very quickly. This rapid formation of PCC crystals provides new PCC fiber complexities in which the PCCs in a cube formation around strands and trades of the MFC. This results in less steric hindrance and high structural strength. A further advantage of this new crystal formation is that it promotes a very pure process without any build-up of PCC in rifir and so on.
    In addition, since PCC is formed around the MFC or nanocellulose and binds tightly to the fiber, the risks of using particles as small as MFC are greatly reduced. Della can be seen as a reduced tendency to dust (in the drying section of the paper machine, when printing, cutting, etc.) especially when large amounts of PCC are used.
    Alternatively, the MFC may be surface modified or mixed with other additives both before and during feeding. These additives can be carboxymethylcellulose (CMC), starch, A-PAM, optical brighteners (OBA), 10 O calcium chloride, PAC or other papermaking chemicals tested for cotton batch applications.
    权利要求:
    Claims (4)
    [1] 1. 4 CLAIMS 1. In-lineproduktionsmetod for att tillhandahalla ett vatskeflode av atminstone ett tillsatsmedel i den korta cirkulationen och in i vatskeflodet av 5 papperstillverkningsmald i en fibervavsmaskin, genom inmatning av vatskeflodet av namnda alminstone ena tillsatsmedel till vatskeflodet i den korta cirkulationen. neir del, firms Eva eller fler tillsatemedel innetatlar metoden vidare att tta dessa att readera mad varandra, varvid metoden innefattar kristalliserind av ett fv1Inadsmede1 och varvid tillsatsmedlen ãr koldioxid och kalciurnhydroxid Eirne milk varvid narnncla koldioxici och kalciurnhvdroxid mates in den korta cirkulationen karak tar iserad av att en lamplig mangd mikrofibrillerad cellulosa eller nanofibrillerad polysackarid tillhandahalls vasentligen samtidigt med inmatningen av vatskeflitidet-ak,4-Raemf4da--alm-4-3-stof4e-.4t-Igi-sat&rw3del.- av namhda tva tillsatsmedei sa att narnnda tsatsmedel rea erar eller startar karnbildninc a cellulosaytan ever .falis ut pa vtan av den mikrofibrilleracie cellulosan och dan enorn bildar sammansattnin- ar med den mikrofibrerade cellulosan.
    [2] 2. Metod onligt krav 1, vaniid ridr det firms tA,sa &liar flora tatsmedel, .n-rlf.:attal=4r-l-e-teden--vidare--att-tEE-Eata-des.sa-att4eage-ra4r4eid--vaarvd-ra. 3. Metod onligt krav 1 olior 2, varvid metodon innolattar kristallisering matas in den korta cirkulationenL 24. Metod enligt p4g4t-a-v---kraveg 14, varvid matningen in i den korta cirkulationen och in i vatskeflodets malsuspension av papperstillverkningsmald utfors genom insprutning av atminstone ett tillsatsmedel och/eller mikrofibrillerad cellulosa in i vatskeflOdet av papperstillverkningsmald.
    [3] 3. Metod enligt nagot av kraven 1-24, varvid matningen in i den korta 35 cirkulationen och in i vatskeflodets malsuspension av papperstillverkningsmald sker genom att spruta in atminstone antingen koldioxid, kalciumhydroxid och/eller mikrofibrillerad cellulosa in i vatskeflodet av papperstillverkningsmald. 4
    [4] 4. Metod enligt nagot av kraven 1-34, varvid koldioxiden, kalciumhydroxiden och/eller den mikrofibrillerade cellulosan matas in separat genom insprutning. Metod enligt nagot av kravenvarvid den mikrofibrillerade cellulosan tillhandahalls i vatskeflodet av papperstillverkningsmald och kalciumhydroxiden och koldioxiden matas in separat eller simultant genom insprutning. 64. Metod enligt nagot av kraven 1-35, varvid kalciumhydroxiden och mikrofibrillerad cellulosa sammanblandas fore insprutning i vatskeflodet av 15 papperstillverkningsmald och koldioxiden matas in separat ifran blandningen av kalciumhydroxid och mikrofibrillerad cellulosa. 7. Metod enligt nagot av kraven 1-35, varvid den mikrofibrillerade cellulosan blandas med andra valfria tillsatsmedel och blandningen matas in 20 separat fran inmatningen av kalk och koldioxid. 8-14. Metod enligt nagot av foregaende krav, varvid insprutningen i vatskeflodet av papperstillverkningsmald genomfors fran ett eller flera munstycken i en riktning vasentligen tvargaende mot vatskeflodets riktning, 25 och i en flOdeshastighet hOgre an den for vatskeflodet. 911. Metod enligt nagot av foregaende krav, varvid vatskeflOdet av papperstillverkningsmald innehaller atminstone en av foljande komponenter: nymassasuspension (langfibermassa, kortfibermassa, mekanisk massa, kemomekanisk massa, kemisk massa, mikrofibermassa, nanofibermassa), atervunnen massasuspension (atervunnen massa, atergangsmassa, fiberfraktioner fran fiberatervinningsfiltret), tillstatssuspension och filtrat innehallande fasta delar.
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    EP2917407A4|2016-06-01|
    SE538250C2|2016-04-12|
    EP2917407B1|2021-03-10|
    CN104903514A|2015-09-09|
    EP2917407A1|2015-09-16|
    CA2890319A1|2014-05-15|
    CA2890319C|2020-10-20|
    PL2917407T3|2021-10-18|
    ES2871057T3|2021-10-28|
    UY35121A|2014-05-30|
    US20150292159A1|2015-10-15|
    US9453305B2|2016-09-27|
    WO2014072914A1|2014-05-15|
    BR112015010599A2|2017-07-11|
    CN104903514B|2018-10-30|
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    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    SE1251278A|SE538250C2|2012-11-09|2012-11-09|In-line production method for papermaking|SE1251278A| SE538250C2|2012-11-09|2012-11-09|In-line production method for papermaking|
    UY0001035121A| UY35121A|2012-11-09|2013-11-05|PAPER MANUFACTURING PROCESS ONLINE PRODUCTION METHOD|
    PL13853131T| PL2917407T3|2012-11-09|2013-11-06|In-line production method for paper making process|
    PCT/IB2013/059946| WO2014072914A1|2012-11-09|2013-11-06|In-line production method for paper making process|
    US14/441,249| US9453305B2|2012-11-09|2013-11-06|In-line production method for paper making process|
    ES13853131T| ES2871057T3|2012-11-09|2013-11-06|In-line production method for a papermaking process|
    CN201380069843.0A| CN104903514B|2012-11-09|2013-11-06|Online production method for paper technology|
    CA2890319A| CA2890319C|2012-11-09|2013-11-06|In-line production method comprising precipitation of calcium carbonate for paper making process|
    EP13853131.4A| EP2917407B1|2012-11-09|2013-11-06|In-line production method for paper making process|
    BR112015010599A| BR112015010599A2|2012-11-09|2013-11-06|method to be implemented on a production line for a papermaking process ".|
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